Organic Chemistry Quiz

Purification & Analysis | Pankaj Sijariya Sir

Q1. Assertion & Reason
Assertion (A): In steam distillation, the liquid boils when p = p1 + p2. [cite: 6]
Reason (R): Since p1 is lower than p, the organic liquid vaporizes at a lower temperature than its boiling point. [cite: 8]
  • (A) Both A and R are correct; R is the correct explanation of A.
  • (B) Both A and R are correct; R is not correct explanation of A.
  • (C) A is correct; R is incorrect.
  • (D) R is correct; A is incorrect.
Correct Answer: A. Because the external pressure is shared, the liquid doesn't need to reach its full boiling point pressure alone. [cite: 9]
Q2. Column Chromatography

Identify labels A and B in the separated mixture:

  • (A) A = b+c, B = c
  • (B) A = K (constant), B = b+c
  • (C) A = a, B = b
  • (D) A = no component, B = a
Correct Answer: A. As the mixture (a+b+c) moves down, components separate into bands based on adsorption. [cite: 27]
Q3. Extraction

Technique where same solvent is repeatedly used:

  • (A) Continuous extraction
  • (B) Non-continuous extraction
  • (C) Differential extraction
  • (D) Non-differential extraction
Correct Answer: A. Continuous extraction allows efficient recovery using minimal solvent volumes. [cite: 33]
Q4. Boiling Points
Assertion (A): Mixture boils close to but lower than 373 K. [cite: 38]
Reason (R): In presence of insoluble substance, boiling point of water decreases. [cite: 39]
  • (A) Both A and R are correct; R is the correct explanation of A.
  • (B) Both A and R are correct; R is not correct explanation of A.
  • (C) A is correct; R is incorrect.
  • (D) R is correct; A is incorrect.
Correct Answer: C. The boiling point of water itself doesn't decrease; the system boils lower because of combined vapor pressures. [cite: 43]
Q5. Colour Removal

Used to remove impurities imparting colour:

  • (A) Activated palladium
  • (B) Activated charcoal
  • (C) Activated nickel
  • (D) All of these
Correct Answer: B. Activated charcoal has a high surface area that adsorbs colored organic impurities. [cite: 48]